You can get ORP probes lots of places, just be careful that the connections are the same if you buy a different brand. Some companies (like the one I work for

) make probes that have the cable permanently attached to the PROBE, some make them with the cable attached to the MONITOR, and some of them it's a separate purchase altogether. There are also two standard connections, a BNC (like a stereo cable) and a DIN (like a computer cable).
You really don't want to calibrate ORP with solution. Most ORP meters and controllers are factory calibrated, which means you'll have to send it back to the manufacturer to have it calibrated. If you must calibrate it, I would use a mV simulator rather than a solution. Too many things can affect solution to alter the ORP; you'll end up making it further rather than closer to calibration.
Cheers,
Jessica