IMO and from what i have read ,most agree that the skimmer should be first in line in the filtration process,also skimmers tend be be affected by varying sump levels.A protien skimmer is the only form of filtration that removes nutrients from the water completely thus making them the most efficient form of filtration so our systems should be designed around them.The absolute best way of feeding a skimmer is to tee it into an overflow with its own valve and then have it return into the sump.This not only make the skimmer more effective but also lightens the load on other filtration methods,ie lenghtens the life of carbon,filter pads,media etc.
I am not saying your set up will not work because it will ,i am just giving my opinion FWIW on how it's potential could be maximized,and this is best done in the planning stages which it looks like you are putting a lot of thought into,hope this helps.
-Liam.